経産省未来開拓研究プロジェクト(2012-2013年度)NEDOプロジェクト(2014-2021年度)有機ケイ素機能性化学品 製造プロセス技術開発(ケイ素プロジェクト)

論文発表

【論文発表】(2021 年 3 月 23 日掲載分まで)

2020 年度 (令和2 年度)  (計 11 件)
11. Palladium-Catalyzed Difunctionalization of 1,3-Diene with Amine and Disilane under a Mild Re-oxidation System
Kazuyuki Torii, Atsushi Kawakubo, Xianjin Lin, Tetsuaki Fujihara, Tatsuo Yajima, Yasushi Obora* (所属:関西大学)
Chem. Euro. J. 2021, 93 (9), 1086 – 1094. DOI: 10.1002/chem.20210043
 
 
10. Synthesis of Tricyclic Laddersiloxane with Various Ring Sizes (Bat Siloxane)
Thanawat Chaiprasert, Yujia Liu, Pa-kwan Intaraprecha, Rungthip Kunthom, Nobuhiro Takeda, Masafumi Unno* (所属:群馬大学)
Macromolecular Rapid Communications 2021, 42 (5), 2000608. DOI: 10.1002/marc.202000608
 
 
9. Facile Synthesis of Sequence-Defined Oligo(dimethylsiloxane-co-diphenylsiloxane)s
Takahiro Kawatsu, Jun-Chul Choi, Kazuhiko Sato, Kazuhiro Matsumoto*(所属:産業技術総合研究所)
Macromolecular Rapid Communications 2021, 42 (5), 2000593. DOI: 10.1002/marc.202000593
 
 
8. Treating Octasilanol [Si8O12][OH]8 with Tetramethoxysilane and Trimethoxyvinylsilane: A Halogen-free Synthetic Route to Alkoxysilyl-substituted Double-four-ring Siloxanes
Takeshi Nozawa, Toshiaki Kobayashi, Tomohiro Matsumoto, Fujio Yagihashi, Kazuhiko Sato, Masayasu Igarashi*(所属:産業技術総合研究所)
Dalton Trans. 2021, 50, 1594-1598. DOI: 10.1039/D0DT04265J
 
 
7. Organocatalytic Ring-opening Polymerization of Cyclotrisiloxanes Using Silanols as Initiators for the Precise Synthesis of Asymmetric Linear Polysiloxanes
Keita Fuchise*, Toshiaki Kobayashi, Kazuhiko Sato*, Masayasu Igarashi*(所属:産業技術総合研究所)
Polymer Chemistry 2020, 11, 7625-7636. DOI: 10.1039/D0PY01251C
 
 
6. Hemisphere and Distance-dependent Steric Analysis of PNN Iron Pincer Complexes using SambVca 2.1 and its Influence on Alkene Hydrosilylation
Masahiro Kamitani*, Kouta Yujiri, and Hidetaka Yuge(所属:北里大学)
Organometallics 2020, 39 (19), 3535-3539. DOI: 10.1021/acs.organomet.0c00512
 
 
5. Synthesis of Tetrachloro, Tetraiodo, and Tetraazido Double-Decker Siloxanes
Yujia Liu, Mana Kigure, Kyoka Koizumi, Nobuhiro Takeda, Masafumi Unno*, Armelle Ouali*(所属:群馬大学)
Inorganic Chemistry 2020, 59 (20), 15478-15486. DOI: 10.102/acs.inorgchem.0c02515
 
 
4. Regioselective Hydrosilylation of Olefins Catalyzed by Co-Iminobipyridine Complexes: The Role of Cyclohexyl Substituent on the Imino Nitrogen
Daisuke Taguchi, Katsuaki Kobayashi,* Toshiyuki Moriuchi, and Hiroshi Nakazawa*(所属:大阪市立大学)
Bull. Chem. Soc. Jpn. 2020, 93 (9), 1086 – 1094. DOI: 10.1246/bcsj.20200043
 
 
3. Direct Transformation of Silica from Natural Resources to Form Tetramethoxysilane
Wahyu S. Putro, Keisuke Fukaya, Jun-Chul Choi, Seong Jib Choi, Toshio Horikoshi, Kazuhiko Sato, Norihisa Fukaya* (所属:産業技術総合研究所)
Bull. Chem. Soc. Jpn. 2020, 93 (8), 958-962. DOI: 10.1246/bcsj.20200054
 
 
2. Catalytic Decarboxylation of Silyl Alkynoates to Alkynylsilanes
Takahiro Kawatsu, Keiya Aoyagi, Yumiko Nakajima, Jun-Chul Choi, Kazuhiko Sato, and Kazuhiro Matsumoto* (所属:産業技術総合研究所)
Organometallics 2020 39 (16), 2947–2950.  DOI: 10.1021/acs.organomet.0c00433
 
 
1. A Catalyst- and Additive-free Synthesis of Alkoxyhydrosiloxanes from Silanols and Alkoxyhydrosilanes
Yasushi Satoh, Keita Fuchise, Takeshi Nozawa, Kazuhiko Sato, Masayasu Igarashi*(所属:産業技術総合研究所)
Chem. Commun. 2020 56, 8218–8221. DOI: 10.1039/d0cc03379k
 
 
2019年度 (平成31 年度・令和元年度)  (計 7 件)
7. Chemoselective Hydrosilylation of Olefin/Ketone Catalyzed by Iminobipyridine Fe and Co Complexes
Katsuaki Kobayashi,* Daisuke Taguchi, Toshiyuki Moriuchi, Hiroshi Nakazawa* (所属:大阪市立大学)
ChemCatChem 2020, 12 (2), 736-739. DOI: 10.1002/cctc.201901717
 
 
6. Synthesis of ‘butterfly cage’ based on double-decker silsesquioxane
Rungthip Kunthom, Takuto Adachi, Yujia Liu, Nobuhiro Takeda, Masafumi Unno, Ryoji Tanaka (所属:群馬大学)
Chemistry, Asian J. 2019, 14 (23), 4179–4182. DOI: 10.1002/asia.201901361
 
 
5. Synthesis and Characterization of Unsymmetrical Double-Decker Siloxane (Basket Cage)
Rungthip Kunthom, Nobuhiro Takeda, Masafumi Unno* (所属:群馬大学)
Molecules 2019, 24 (23), 4252–4259. DOI: 10.3390/molecules24234252
 
 
4. Impact of Water Removal Method on Tetraethyl Orthosilicate Direct Synthesis: Experiment and Process Assessment
Thuy T. H. Nguyen*, Norihisa Fukaya*, Seong Jib Choi, Kazuhiko Sato, Jun-Chul Choi, and Sho Kataoka* (所属:産業技術総合研究所)
Ind. Eng. Chem. Res. 2019, 58 (43), 19997-20002. DOI: 10.1021/acs.iecr.9b02887
 
 
3. Hydrosilylation of Ketones Catalyzed by Iron Iminobipyridine Complexes and Accelerated by Lewis Bases
Katsuaki Kobayashi*, Yosuke Izumori, Daisuke Taguchi, Hiroshi Nakazawa* (所属:大阪市立大学)
ChemPlusChem 2019, 84 (8), 1094-1102. DOI: 10.1002/cplu.201900366
 
 
2. Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation and Elucidation of its Activation Mechanism
Masahiro Kamitani*, Haruki Kusaka , and Hidetaka Yuge (所属:北里大学)
Chem. Lett. 2019, 48 (10), 1196-1198. DOI: 10.1246/cl.190521
 
 
1. Dimethylformamide-Stabilized Palladium Nanoclusters Catalyzed Coupling Reactions of Aryl Halides with Hydrosilanes/Disilanes
Tatsuki Nagata, Takeru Inoue, Xianjin Lin, Shinya Ishimoto, Seiya Nakamichi, Hideo Oka, Ryota Kondo, Takeyuki Suzuki and Yasushi Obora (所属:関西大学)
RSC Advances 2019, 9, 17425-17431. DOI: 10.1039/C9RA02895A
 
 
2018 年度 (平成30 年度)(計 9 件)
9. Mechanistic Details on the Conversion of Si–O to Si–C Bonds using Metal Hydrides: A Density Functional Theory Study
Valeria Butera, Norihisa Fukaya, Jun‐Chul Choi, Kazuhiko Sato, Yoong‐Kee Choe* (所属:産業技術総合研究所)
Eur. J. Inorg. Chem. 2019, (10), 1335–1342. DOI: 10.1002/ejic.201900039
 
 
8. Synthesis of Double-Decker Silsesquioxanes from Substituted Difluorosilane
Toru Tanaka*, Yasuharu Hasegawa, Takashi Kawamori, Rungthip Kunthom, Nobuhiro Takeda, Masafumi Unno* (所属:群馬大学)
Organometallics 2019, 38 (4), 743-747. DOI: 10.1021/acs.organomet.8b00896
 
 
7. Sequence-Controlled Catalytic One-Pot Synthesis of Siloxane Oligomers
Kazuhiro Matsumoto*, Shigeru Shimada, Kazuhiko Sato (所属:産業技術総合研究所)
Chem. Eur. J. 2019, 25 (4), 920−928. DOI: 10.1002/chem.201803565
 
 
6. Hydrosilylation of Diene Derivatives Catalyzed by Fe-Iminobipyridine Complexes Aiming at Syntheses of Organosilane Compounds Containing a Terminal Olefin Portion
Katsuaki Kobayashi*, Sayaka Teratani, Yosuke Izumori, Kazumasa Hayasaka, Hiroshi Nakazawa* (所属:大阪市立大学)
Bull. Chem. Soc. Jpn. 2019, 92 (1), 105–114. DOI: 10.1246/bcsj.20180197
 
 
5. [Si8O12][OH]8: Isolation, Structure, and Reactivity of a Cubic Octamer of Orthosilicic Acid
Takeshi Nozawa, Tomohiro Matsumoto, Fujio Yagihashi, Teruo Beppu, Kazuhiko Sato*, Masayasu Igarashi* (所属:産業技術総合研究所)
Chem. Lett. 2018, 47 (12), 1530-1533. DOI: 10.1246/cl.180776
 
 
4. Solution Synthesis of N,N-Dimethylformamide-stabilized Iron Oxide Nanoparticles as an Efficient and Recyclable Catalyst for Alkene Hydrosilylation
Azuma, S. Nakamichi, J. Kimura, H. Yano, H. Kawasaki, T. Suzuki, R. Kondo, Y. Kanda, K. Shimizu, K. Kato, Y. Obora* (所属:関西大学)
ChemCatChem 2018, 10 (11), 2378-2382. DOI: 10.1002/cctc.201800161
 
 
3. Alkoxysilane production from silica and dimethylcarbonate catalyzed by alkali bases: A quantum chemical investigation of the reaction mechanism
Valeria Butera, Norihisa Fukaya, Jun-Chul Choi, Kazuhiko Sato, Yoong-Kee Choe*  (所属:産業技術総合研究所)
Inorg. Chim. Acta 2018, 482, 70-76. doi:10.1016/j.ica.2018.05.036
Abstract Image
 
2. One‐Pot Sequence‐Controlled Synthesis of Oligosiloxanes
Kazuhiro Matsumoto*, Yuki Oba, Yumiko Nakajima, Shigeru Shimada*, Kazuhiko Sato* (所属:産業技術総合研究所)
Angew. Chem. Int. Ed. 2018, 57, 4637-4641. doi:10.1002/anie.201801031
 
 
1. Direct Silyl–Heck Reaction of Chlorosilanes
Kazuhiro Matsumoto, Jiadi Huang, Yuki Naganawa, Haiqing Guo, Teruo Beppu, Kazuhiko Sato, Shigeru Shimada*, Yumiko Nakajima* (所属:産業技術総合研究所)
Org. Lett. 2018, 20, 2481-2484. doi:10.1021/acs.orglett.8b00847 
 
 
2017 年度(平成 29 年度) (計 7 件)
7. Organocatalytic Controlled/Living Ring-Opening Polymerization of Cyclotrisiloxanes Initiated by Water with Strong Organic Base Catalysts
Keita Fuchise*, Masayasu Igarashi, Kazuhiko Sato*, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Sci. 2018, 9, 2879-2891. doi:10.1039/C7SC04234E (Open Access)
Graphical abstract: Back cover      Graphical abstract: Organocatalytic controlled/living ring-opening polymerization of cyclotrisiloxanes initiated by water with strong organic base catalysts
  
6. Technoeconomic and environmental assessment for design and optimization of tetraethyl orthosilicate synthesis process
Thuy T. H. Nguyen*, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi, Sho Kataoka* (所属:産業技術総合研究所)
Ind. Eng. Chem. Res. 2018, 57, 2192-2199. DOI: 10.1021/acs.iecr.7b03895
Abstract Image
  
5. Hybrid Lead Halide Layered Perovskites with Silsesquioxane Interlayers
Sho Kataoka, Wako Kaburagi, Hiroyuki Mochizuki, Yoshihiro Kamimura, Kazuhiko Sato, Akira Endo (所属:産業技術総合研究所)
J. Nanosci. Nanotechnol. 2018, 18, 95–99. DOI: 10.1166/jnn.2018.14617
(No Image)
  
4. Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins
Venu Srinivas, Yumiko Nakajima*, Kazuhiko Sato, Sigeru Shimada* (所属:産業技術総合研究所)
Org. Lett. 2018, 20, 12-15.   DOI: 10.1021/acs.orglett.7b02940
Abstract Image
  
3. Feasibility study of new synthesis route of tetraethoxysilane from rice hull ash
Thuy T. H. Nguyen*, Sho Kataoka, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi, Akira Endo (所属:産業技術総合研究所)
Comput. Aided Chem. Eng. 2017, 40, 703-708. Doi: 10.1016/B978-0-444-63965-3.50119-7
(No Image)
  
2. Non-aqueous selective synthesis of orthosilicic acid and its oligomers
Masayasu Igarashi,1 Tomohiro Matsumoto,1 Fujio Yagihashi,1 Hiroshi Yamashita,1 Takashi Ohhara,2 Takayasu Hanashima,3 Akiko Nakao,3 Taketo Moyoshi,3 Kazuhiko Sato*,1 Shigeru Shimada*1 (所属:1産業技術総合研究所, 2 日本原子力機構, 3総合科学研究機構 )
Nature Commun. 2017, 8, 140. DOI: 10.1038/s41467-017-00168-5 (Open Access)
  Fig. 1    Fig. 2
  
1. Tris(pentafluorophenyl)borane-Catalyzed Reaction of Siloxanes: A Combined Experimental and Computational Study
Jomon Mathew, Katsuya Eguchi, Yumiko Nakajima, Kazuhiko Sato, Shigeru Shimada,* Yoong-Kee Choe*  (所属:産業技術総合研究所)
Eur. J. Org. Chem. 2017, 33, 4922–4927. DOI:10.1002/ejoc.201700760
2016 年度(平成 28 年度) (計 14 件)
14.Direct Synthesis of Tetraalkoxysilane from Silica and Alcohol
 Norihisa Fukaya*, Seong Jib Choi, Toshio Horikoshi, Sho Kataoka, Akira Endo, Hiroshi Kumai, Minoru Hasegawa, Kazuhiko Sato , Jun-Chul Choi*  (所属:産業技術総合研究所、コルコート株式会社)
New J. Chem. 2017, 41, 2224-2226. DOI: 10.1039/c6nj03897b
Graphical abstract: Direct synthesis of tetraalkoxysilanes from silica and alcohols
13. 砂や灰などからの有機ケイ素原料の効率的な合成法の開発
 深谷訓久、崔準哲  (所属:産業技術総合研究所)
月刊機能材料201737, 52-56.出版社のサイト
 
 12. By-Product-Free Siloxane-Bond Formation and Programmed One-Pot Oligosiloxane Synthesis
 Kazuhiro Matsumoto, Kappam Veettil Sajna, Yasushi Satoh, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Angew. Chem. Int. Ed. 2017, 56, 3168-3171. DOI: 10.1002/anie.201611623
  
 
11. Highly Selective Synthesis of Hydrosiloxanes by Au-Catalyzed Dehydrogenative Cross-Coupling Reaction of Silanols with Hydrosilanes
  Yasushi Satoh, Masayasu Igarashi, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
 ACS Catal. 2017, 7, 1836−1840.  DOI: 10.1021/acscatal.6b03560
Abstract Image
 
10. ケイ素化学品原料製造の現状と展望
 深谷訓久、崔準哲  (所属:産業技術総合研究所)
工業材料201765 (1), 45-48.出版社のサイト
 
9. Selective Formation of Alkoxychlorosilanes and Organotrialkoxysilane with Four Different Substituents by Intermolecular Exchange Reaction
 Yuma Komata, Masashi Yoshikawa, Yasuhiro Tamura, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda* (所属:早稲田大学)
Chem. Asian J. 2016, 11, 3225–3233. DOI:10.1002/asia.201601120
 
8. Controlled Formation of Ordered Coordination Polymeric Networks Using Silsesquioxane Building Block
 Subhabrata Banerjee, Sho Kataoka, Toshikazu Takahashi, Yoshihiro Kamimura, Kunio Suzuki, Kazuhiko Sato, Akira Endo*
Dalton Trans. 2016, 45, 17082–17086. DOI: 10.1039/c6dt02868c  (所属:産業技術総合研究所)
Graphical abstract: Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks
 
7. Development of Nickel Hydrosilylation Catalysts
 Yumiko Nakajima*, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Rec. 2016, 16, 2379–2387. DOI: 10.1002/tcr.201600056
 
6. Synthesis of dimethylmanganese(II) complexes bearing N-heterocyclic carbenes and nucleophilic substitution reaction of tetraalkoxysilanes by diorganomanganese(II) complexes
Takayoshi Hashimoto, Yuko Kawato, Yumiko Nakajima*, Yasuhiro Ohki, Kazuyuki Tatsumi, Wataru Ando, Kazuhiko Sato, Shigeru Shimada*  (所属:産業技術総合研究所)
J. Orgnomet. Chem. 2016, 820, 14-19. Doi:10.1016/j.jorganchem.2016.07.025
 
5. Unexpected Selectivity in the Cyclotetrasiloxane Formation by the Hydrolytic Condensation Reaction of Trichloro(phenyl)silane
Fujio Yagihashi*, Masayasu Igarashi, Yumiko Nakajima, Kazuhiko Sato, Yoshiyuki Yumoto, Chinami Matsui and Shigeru Shimada*  (所属:産業技術総合研究所)
Eur. J. Inorg. Chem. 2016, 2882–2886. DOI: 10.1002/ejic.201600454
 
4. Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation
Naoki Oguri, Yasunobu Egawa, Nobuhiro Takeda, Masafumi Unno* (所属:群馬大学)
Angew. Chem. Int. Ed. 2016, 55, 9336–9339. DOI: 10.1002/anie.201602413
  
 
3. Synthesis of Tetramethoxysilane from Silica and Methanol using Carbon Dioxide and an Organic Dehydrating Reagent
Norihisa Fukaya*, Seong Jib Choi, Toshio Horikoshi, Hiroshi Kumai, Minoru, hasegawa, Hiroyuki Yasuda, Kazuhiko Sato, Jun-Chul Choi* (所属:産業技術総合研究所)
Chem. Lett. 2016, 45, 828-830.   Doi:10.1246/cl.160329
figure
 
2. Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials
Yasunobu Egawa, Shinji Murakami, Nobuhiro Takeda, Masafumi Unno*  (所属:群馬大学)
Chem. Lett. 2016, 45, 738–739. Doi:10.1246/cl.160272
figure
 
1. Olefin hydrosilylation catalyzed by cationic nickel(II) allyl complexes: a non-innocent allyl ligand-assisted mechanism
Jomon Mathew, Yumiko Nakajima*, Yoong-Kee Choe, Yasuko Urabe, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Commun. 2016, 52, 6723-6726. DOI: 10.1039/c6cc01665k
Graphical abstract: Olefin hydrosilylation catalyzed by cationic nickel(ii) allyl complexes: a non-innocent allyl ligand-assisted mechanism
2015 年度(平成 27 年度)  (計 3 件)
3. Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes
Venu Srinivas, Yumiko Nakajima*, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
J. Organomet. Chem. 2016, 809, 57-62. doi:10.1016/j.jorganchem.2016.02.025
  
2. Highly Efficient Olefin Hydrosilylation Catalyzed by Iron Complexes with Iminobipyridine Ligand
Kazumasa Hayasaka, Kouji Kamata, Hiroshi Nakazawa* (所属:大阪市立大学)
Bull. Chem. Soc. Jpn. 2016, 89, 394–404. doi:10.1246/bcsj.20150359
figure

 
1. Palladium-Catalyzed Oxidative Silylation of Simple Olefins to give Allylsilanes Using Hexamethyldisilane and Molecular Oxygen as the Sole Oxidant
Syunji Nakai, Masaki Matsui, Yosuke Shimizu, Yurina Adachi, Yasushi Obora* (所属:関西大学)
J. Org. Chem. 2015, 80, 7317−7320. DOI: 10.1021/acs.joc.5b01216
Abstract Image
2014 年度(平成 26 年度)  (計 5 件)
5. Layered Hybrid Perovslites with Micropores Created by Alkylammonium Functional Silsesquioxane Interlayers
Sho Kataoka,* Subhabrata Banerjee, Akiko Kawai, Yoshihiro Kamimura, Jun-Chul Choi, Tetsuya Kodaira, Kazuhiko Sato, Akira Endo* (所属:産業技術総合研究所)
J. Am. Chem. Soc. 2015, 137, 4158–4163. DOI: 10.1021/jacs.5b00290
Abstract Image
 
4. (Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins
Venu Srinivas, Yumiko Nakajima*, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Catal. Sci. Technol. 2015, 5, 2081–2084. DOI: 10.1039/c5cy00270b
Graphical abstract: (Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins
 
3. Acid-Catalyzed Condensation Reaction of Phenylsilanetriol: Unexpected Formation of cis,trans-1,3,5-Trihydroxy-1,3,5-triphenylcyclotrisiloxane as the Main Product and Its Isolation
Fujio Yagihashi, Masayasu Igarashi, Yumiko Nakajima, Wataru Ando, Kazuhiko Sato, Yoshiyuki Yumoto, Chinami Matsui, Shigeru Shimada* (所属:産業技術総合研究所)
Organometallics 2014, 33, 6278−6281. DOI: 10.1021/om500691c
Abstract Image
 
2. Pd/C-Catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes
Masayasu Igarashi, Keiko Kubo, Tomohiro Matsumoto, Kazuhiko Sato, Wataru Ando, Shigeru Shimada* (所属:産業技術総合研究所)
RSC Adv. 2014, 4, 19099–19102. DOI: 10.1039/c4ra02126f
Graphical abstract: Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes
 
1. Nonhydrolytic Synthesis of Silanols by the Hydrogenolysis of Benzyloxysilanes
Masayasu Igarashi, Tomohiro Matsumoto, Kazuhiko Sato, Wataru Ando, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Lett. 2014, 43, 429–431.doi:10.1246/cl.131079
figure

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