経産省未来開拓研究プロジェクト(平成24-25年度)NEDOプロジェクト(平成26-33年度)有機ケイ素機能性化学品 製造プロセス技術開発(ケイ素プロジェクト)

論文発表

【論文発表】(2018 年 7 月 18 日公開分まで)

平成 30 年度 (2018 年度)
2. Alkoxysilane production from silica and dimethylcarbonate catalyzed by alkali bases: A quantum chemical investigation of the reaction mechanism
Valeria Butera, Norihisa Fukaya, Jun-Chul Choi, Kazuhiko Sato, Yoong-Kee Choe*  (所属:産業技術総合研究所)
Inorg. Chim. Acta 2018, 482, 70-76. doi:10.1016/j.ica.2018.05.036
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1. Direct Silyl–Heck Reaction of Chlorosilanes
Kazuhiro Matsumoto, Jiadi Huang, Yuki Naganawa, Haiqing Guo, Teruo Beppu, Kazuhiko Sato, Shigeru Shimada*, Yumiko Nakajima*  (所属:産業技術総合研究所)
Org. Lett. 2018, 20, 2481-2484. doi:10.1021/acs.orglett.8b00847
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平成 29 年度 (2017 年度) (計 8 件)
8. One‐Pot Sequence‐Controlled Synthesis of Oligosiloxanes
Kazuhiro Matsumoto*, Yuki Oba, Yumiko Nakajima, Shigeru Shimada*, Kazuhiko Sato* (所属:産業技術総合研究所)
Angew. Chem. Int. Ed. 2018, 57, 4637-4641. doi:10.1002/anie.201801031
  
7. Organocatalytic Controlled/Living Ring-Opening Polymerization of Cyclotrisiloxanes Initiated by Water with Strong Organic Base Catalysts
Keita Fuchise*, Masayasu Igarashi, Kazuhiko Sato*, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Sci. 2018, 9, 2879-2891. doi:10.1039/C7SC04234E (Open Access)
Graphical abstract: Back cover      Graphical abstract: Organocatalytic controlled/living ring-opening polymerization of cyclotrisiloxanes initiated by water with strong organic base catalysts
  
6. Technoeconomic and environmental assessment for design and optimization of tetraethyl orthosilicate synthesis process
Thuy T. H. Nguyen*, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi, Sho Kataoka* (所属:産業技術総合研究所)
Ind. Eng. Chem. Res. 2018, 57, 2192-2199. DOI: 10.1021/acs.iecr.7b03895
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5. Hybrid Lead Halide Layered Perovskites with Silsesquioxane Interlayers
Sho Kataoka, Wako Kaburagi, Hiroyuki Mochizuki, Yoshihiro Kamimura, Kazuhiko Sato, Akira Endo (所属:産業技術総合研究所)
J. Nanosci. Nanotechnol. 2018, 18, 95–99. DOI: 10.1166/jnn.2018.14617
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4. Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins
Venu Srinivas, Yumiko Nakajima*, Kazuhiko Sato, Sigeru Shimada* (所属:産業技術総合研究所)
Org. Lett. 2018, 20, 12-15.   DOI: 10.1021/acs.orglett.7b02940
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3. Feasibility study of new synthesis route of tetraethoxysilane from rice hull ash
Thuy T. H. Nguyen*, Sho Kataoka, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi, Akira Endo (所属:産業技術総合研究所)
Comput. Aided Chem. Eng. 2017, 40, 703-708. Doi: 10.1016/B978-0-444-63965-3.50119-7
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2. Non-aqueous selective synthesis of orthosilicic acid and its oligomers
Masayasu Igarashi,1 Tomohiro Matsumoto,1 Fujio Yagihashi,1 Hiroshi Yamashita,1 Takashi Ohhara,2 Takayasu Hanashima,3 Akiko Nakao,3 Taketo Moyoshi,3 Kazuhiko Sato*,1 Shigeru Shimada*1 (所属:1産業技術総合研究所, 2 日本原子力機構, 3総合科学研究機構 )
Nature Commun. 2017, 8, 140. DOI: 10.1038/s41467-017-00168-5 (Open Access)
  Fig. 1    Fig. 2
  
1. Tris(pentafluorophenyl)borane-Catalyzed Reaction of Siloxanes: A Combined Experimental and Computational Study
Jomon Mathew, Katsuya Eguchi, Yumiko Nakajima, Kazuhiko Sato, Shigeru Shimada,* Yoong-Kee Choe*  (所属:産業技術総合研究所)
Eur. J. Org. Chem. 2017, 33, 4922–4927. DOI:10.1002/ejoc.201700760

 

平成 28 年度 (2016 年度) (計 14 件)
14.Direct Synthesis of Tetraalkoxysilane from Silica and Alcohol
 Norihisa Fukaya*, Seong Jib Choi, Toshio Horikoshi, Sho Kataoka, Akira Endo, Hiroshi Kumai, Minoru Hasegawa, Kazuhiko Sato , Jun-Chul Choi*  (所属:産業技術総合研究所、コルコート株式会社)
New J. Chem. 2017, 41, 2224-2226. DOI: 10.1039/c6nj03897b
Graphical abstract: Direct synthesis of tetraalkoxysilanes from silica and alcohols
13. 砂や灰などからの有機ケイ素原料の効率的な合成法の開発
 深谷訓久、崔準哲  (所属:産業技術総合研究所)
月刊機能材料201737, 52-56.出版社のサイト
 
 12. By-Product-Free Siloxane-Bond Formation and Programmed One-Pot Oligosiloxane Synthesis
 Kazuhiro Matsumoto, Kappam Veettil Sajna, Yasushi Satoh, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Angew. Chem. Int. Ed. 2017, 56, 3168-3171. DOI: 10.1002/anie.201611623
  
 
11. Highly Selective Synthesis of Hydrosiloxanes by Au-Catalyzed Dehydrogenative Cross-Coupling Reaction of Silanols with Hydrosilanes
  Yasushi Satoh, Masayasu Igarashi, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
 ACS Catal. 2017, 7, 1836−1840.  DOI: 10.1021/acscatal.6b03560
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10. ケイ素化学品原料製造の現状と展望
 深谷訓久、崔準哲  (所属:産業技術総合研究所)
工業材料201765 (1), 45-48.出版社のサイト
 
9. Selective Formation of Alkoxychlorosilanes and Organotrialkoxysilane with Four Different Substituents by Intermolecular Exchange Reaction
 Yuma Komata, Masashi Yoshikawa, Yasuhiro Tamura, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda* (所属:早稲田大学)
Chem. Asian J. 2016, 11, 3225–3233. DOI:10.1002/asia.201601120
 
8. Controlled Formation of Ordered Coordination Polymeric Networks Using Silsesquioxane Building Block
 Subhabrata Banerjee, Sho Kataoka, Toshikazu Takahashi, Yoshihiro Kamimura, Kunio Suzuki, Kazuhiko Sato, Akira Endo*
Dalton Trans. 2016, 45, 17082–17086. DOI: 10.1039/c6dt02868c  (所属:産業技術総合研究所)
Graphical abstract: Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks
 
7. Development of Nickel Hydrosilylation Catalysts
 Yumiko Nakajima*, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Rec. 2016, 16, 2379–2387. DOI: 10.1002/tcr.201600056
 
6. Synthesis of dimethylmanganese(II) complexes bearing N-heterocyclic carbenes and nucleophilic substitution reaction of tetraalkoxysilanes by diorganomanganese(II) complexes
Takayoshi Hashimoto, Yuko Kawato, Yumiko Nakajima*, Yasuhiro Ohki, Kazuyuki Tatsumi, Wataru Ando, Kazuhiko Sato, Shigeru Shimada*  (所属:産業技術総合研究所)
J. Orgnomet. Chem. 2016, 820, 14-19. Doi:10.1016/j.jorganchem.2016.07.025
 
5. Unexpected Selectivity in the Cyclotetrasiloxane Formation by the Hydrolytic Condensation Reaction of Trichloro(phenyl)silane
Fujio Yagihashi*, Masayasu Igarashi, Yumiko Nakajima, Kazuhiko Sato, Yoshiyuki Yumoto, Chinami Matsui and Shigeru Shimada*  (所属:産業技術総合研究所)
Eur. J. Inorg. Chem. 2016, 2882–2886. DOI: 10.1002/ejic.201600454
 
4. Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation
Naoki Oguri, Yasunobu Egawa, Nobuhiro Takeda, Masafumi Unno* (所属:群馬大学)
Angew. Chem. Int. Ed. 2016, 55, 9336–9339. DOI: 10.1002/anie.201602413
  
 
3. Synthesis of Tetramethoxysilane from Silica and Methanol using Carbon Dioxide and an Organic Dehydrating Reagent
Norihisa Fukaya*, Seong Jib Choi, Toshio Horikoshi, Hiroshi Kumai, Minoru, hasegawa, Hiroyuki Yasuda, Kazuhiko Sato, Jun-Chul Choi* (所属:産業技術総合研究所)
Chem. Lett. 2016, 45, 828-830.   Doi:10.1246/cl.160329
figure
 
2. Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials
Yasunobu Egawa, Shinji Murakami, Nobuhiro Takeda, Masafumi Unno*  (所属:群馬大学)
Chem. Lett. 2016, 45, 738–739. Doi:10.1246/cl.160272
figure
 
1. Olefin hydrosilylation catalyzed by cationic nickel(II) allyl complexes: a non-innocent allyl ligand-assisted mechanism
Jomon Mathew, Yumiko Nakajima*, Yoong-Kee Choe, Yasuko Urabe, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Commun. 2016, 52, 6723-6726. DOI: 10.1039/c6cc01665k
Graphical abstract: Olefin hydrosilylation catalyzed by cationic nickel(ii) allyl complexes: a non-innocent allyl ligand-assisted mechanism

 

平成 27 年度 (2015 年度)  (計 3 件)
3. Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes
Venu Srinivas, Yumiko Nakajima*, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
J. Organomet. Chem. 2016, 809, 57-62. doi:10.1016/j.jorganchem.2016.02.025
  
2. Highly Efficient Olefin Hydrosilylation Catalyzed by Iron Complexes with Iminobipyridine Ligand
Kazumasa Hayasaka, Kouji Kamata, Hiroshi Nakazawa* (所属:大阪市立大学)
Bull. Chem. Soc. Jpn. 2016, 89, 394–404. doi:10.1246/bcsj.20150359
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1. Palladium-Catalyzed Oxidative Silylation of Simple Olefins to give Allylsilanes Using Hexamethyldisilane and Molecular Oxygen as the Sole Oxidant
Syunji Nakai, Masaki Matsui, Yosuke Shimizu, Yurina Adachi, Yasushi Obora* (所属:関西大学)
J. Org. Chem. 2015, 80, 7317−7320. DOI: 10.1021/acs.joc.5b01216
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平成 26 年度 (2014 年度)  (計 5 件)
5. Layered Hybrid Perovslites with Micropores Created by Alkylammonium Functional Silsesquioxane Interlayers
Sho Kataoka,* Subhabrata Banerjee, Akiko Kawai, Yoshihiro Kamimura, Jun-Chul Choi, Tetsuya Kodaira, Kazuhiko Sato, Akira Endo* (所属:産業技術総合研究所)
J. Am. Chem. Soc. 2015, 137, 4158–4163. DOI: 10.1021/jacs.5b00290
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4. (Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins
Venu Srinivas, Yumiko Nakajima*, Wataru Ando, Kazuhiko Sato, Shigeru Shimada* (所属:産業技術総合研究所)
Catal. Sci. Technol. 2015, 5, 2081–2084. DOI: 10.1039/c5cy00270b
Graphical abstract: (Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins
 
3. Acid-Catalyzed Condensation Reaction of Phenylsilanetriol: Unexpected Formation of cis,trans-1,3,5-Trihydroxy-1,3,5-triphenylcyclotrisiloxane as the Main Product and Its Isolation
Fujio Yagihashi, Masayasu Igarashi, Yumiko Nakajima, Wataru Ando, Kazuhiko Sato, Yoshiyuki Yumoto, Chinami Matsui, Shigeru Shimada* (所属:産業技術総合研究所)
Organometallics 2014, 33, 6278−6281. DOI: 10.1021/om500691c
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2. Pd/C-Catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes
Masayasu Igarashi, Keiko Kubo, Tomohiro Matsumoto, Kazuhiko Sato, Wataru Ando, Shigeru Shimada* (所属:産業技術総合研究所)
RSC Adv. 2014, 4, 19099–19102. DOI: 10.1039/c4ra02126f
Graphical abstract: Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes
 
1. Nonhydrolytic Synthesis of Silanols by the Hydrogenolysis of Benzyloxysilanes
Masayasu Igarashi, Tomohiro Matsumoto, Kazuhiko Sato, Wataru Ando, Shigeru Shimada* (所属:産業技術総合研究所)
Chem. Lett. 2014, 43, 429–431.doi:10.1246/cl.131079
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